By Yaushi Nishihara (auth.), Yasushi Nishihara (eds.)
“Applied Cross-Coupling Reactions” presents scholars and lecturers of complex natural chemistry with an summary of the historical past, mechanisms and functions of cross-coupling reactions. because the discovery of the transition-metal-catalyzed cross-coupling reactions in 1972, a number of man made makes use of and business purposes were built. The mechanistic stories of the cross-coupling reactions have disclosed that 3 primary reactions: oxidative addition, transmetalation, and reductive removal, are serious about a catalytic cycle. Cross-coupling reactions have allowed us to provide various compounds for business reasons, corresponding to traditional items, prescribed drugs, liquid crystals and conjugate polymers to be used in digital units. certainly, the Nobel Prize for Chemistry in 2010 used to be provided for paintings on cross-coupling reactions. during this ebook, the new traits in cross-coupling reactions also are brought from the perspective of synthesis layout and catalytic actions of transition-metal catalysts.
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B-carotene (Fig. 1). Since these compounds possess multi-substituted polyene motifs, a synthetic strategy that selectively introduces the substituents in appropriate positions is necessary. 3 Natural Product Synthesis 53 α -carotene OH vitamin A β -carotene O OH HO astaxanthin O Fig. 1 Representative examples of carotenoids Because these conjugated polyene-type natural products are organic compounds with valuable antioxidant property, efficient and selective innovation for synthetic methods is still actively sought.
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